{"id":2248,"date":"2021-08-09T13:45:34","date_gmt":"2021-08-09T13:45:34","guid":{"rendered":"https:\/\/wldstainless.com\/?p=2248"},"modified":"2021-08-09T13:46:53","modified_gmt":"2021-08-09T13:46:53","slug":"how-the-alloying-element-affect-the-stainless-steel","status":"publish","type":"post","link":"https:\/\/wldstainless.com\/cs\/how-the-alloying-element-affect-the-stainless-steel\/","title":{"rendered":"Jak leguj\u00edc\u00ed prvek ovliv\u0148uje nerezovou ocel?"},"content":{"rendered":"<p>Chemick\u00e9 slo\u017een\u00ed m\u00e1 velk\u00fd vliv na mikrostrukturu, mechanick\u00e9 vlastnosti, fyzik\u00e1ln\u00ed vlastnosti a korozn\u00ed odolnost oceli. Chrom, molybden, nikl a dal\u0161\u00ed leguj\u00edc\u00ed prvky mohou nahradit vrchol \u00dahel austenitov\u00e9 m\u0159\u00ed\u017eky a st\u0159ed \u0161esti stran krychle \u017eelezo, uhl\u00edk a dus\u00edk jsou um\u00edst\u011bny v meze\u0159e mezi atomy m\u0159\u00ed\u017eky (gap position) kv\u016fli mal\u00e9mu objemu , vytv\u00e1\u0159ej\u00ed obrovsk\u00e9 nap\u011bt\u00ed v m\u0159\u00ed\u017ece, tak\u017ee se st\u00e1vaj\u00ed \u00fa\u010dinn\u00fdmi zpev\u0148uj\u00edc\u00edmi prvky. R\u016fzn\u00e9 leguj\u00edc\u00ed prvky maj\u00ed r\u016fzn\u00e9 \u00fa\u010dinky na vlastnosti oceli, n\u011bkdy prosp\u011b\u0161n\u00e9 a n\u011bkdy \u0161kodliv\u00e9. Hlavn\u00ed leguj\u00edc\u00ed prvky austenitick\u00e9 nerezov\u00e9 oceli maj\u00ed n\u00e1sleduj\u00edc\u00ed \u00fa\u010dinky:<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Cr<\/strong><\/p>\n<p>Chrom je leguj\u00edc\u00ed prvek, d\u00edky kter\u00e9mu je nerezov\u00e1 ocel \u201enerezov\u00e1\u201c. K vytvo\u0159en\u00ed povrchov\u00e9ho pasiva\u010dn\u00edho filmu charakteristick\u00e9 pro nerezovou ocel je zapot\u0159eb\u00ed alespo\u0148 10,51 TP3T chromu. Pasiva\u010dn\u00ed film m\u016f\u017ee zp\u016fsobit, \u017ee nerezov\u00e1 ocel \u00fa\u010dinn\u011b odol\u00e1v\u00e1 korozivn\u00ed vod\u011b, r\u016fzn\u00fdm kysel\u00fdm roztok\u016fm a dokonce i siln\u00e9 oxidaci vysokoteplotn\u00ed plynov\u00e9 koroze. Kdy\u017e obsah chr\u00f3mu p\u0159ekro\u010d\u00ed 10,5%, odolnost nerezov\u00e9 oceli proti korozi se zv\u00fd\u0161\u00ed. Obsah chromu <a href=\"https:\/\/wldstainless.com\/materials\/austenitic-stainless-steel\/304-304l-stainless-steel\/\">304<\/a> nerezov\u00e1 ocel je 18% a n\u011bkter\u00e9 vysoce kvalitn\u00ed austenitick\u00e9 nerezov\u00e9 oceli maj\u00ed obsah chr\u00f3mu a\u017e 20% a\u017e 28%.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Ni<\/strong><\/p>\n<p>Nikl m\u016f\u017ee tvo\u0159it a stabilizovat austenitickou f\u00e1zi. V\u00fdrobce 8%Ni <a href=\"https:\/\/wldstainless.com\/materials\/austenitic-stainless-steel\/304-304l-stainless-steel\/\">304 nerezov\u00e1 ocel<\/a>, kter\u00e9 mu prop\u016fj\u010duj\u00ed mechanick\u00e9 vlastnosti, pevnost a hou\u017eevnatost, kter\u00e9 austenit vy\u017eaduje. Vysoce v\u00fdkonn\u00e9 austenitick\u00e9 nerezov\u00e9 oceli obsahuj\u00ed vysok\u00e9 koncentrace chr\u00f3mu a molybdenu a nikl se p\u0159id\u00e1v\u00e1 k udr\u017een\u00ed austenitick\u00e9 struktury, kdy\u017e je do oceli p\u0159id\u00e1no v\u00edce chr\u00f3mu nebo jin\u00fdch prvk\u016f tvo\u0159\u00edc\u00edch ferit. Struktura austenitu m\u016f\u017ee b\u00fdt zaru\u010dena obsahem niklu asi 20% a odolnost korozivzdorn\u00e9 oceli proti korozi pod nap\u011bt\u00edm lze v\u00fdrazn\u011b zlep\u0161it.<\/p>\n<p>Nikl m\u016f\u017ee tak\u00e9 sn\u00ed\u017eit rychlost kalen\u00ed b\u011bhem deformace za studena, tak\u017ee slitiny pou\u017e\u00edvan\u00e9 pro hlubok\u00e9 ta\u017een\u00ed, zvl\u00e1k\u0148ov\u00e1n\u00ed a ra\u017een\u00ed za studena maj\u00ed obecn\u011b vysok\u00fd obsah niklu.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Mo<\/strong><\/p>\n<p>Molybden zlep\u0161uje odolnost nerezov\u00e9 oceli proti d\u016flkov\u00e9 a \u0161t\u011brbinov\u00e9 korozi v chloridov\u00e9m prost\u0159ed\u00ed. Kombinace molybdenu a chr\u00f3mu, zejm\u00e9na dus\u00edku, zp\u016fsobuje, \u017ee vysoce v\u00fdkonn\u00e1 austenitick\u00e1 nerezov\u00e1 ocel m\u00e1 silnou odolnost proti d\u016flkov\u00e9 a \u0161t\u011brbinov\u00e9 korozi. Mo m\u016f\u017ee tak\u00e9 zlep\u0161it odolnost nerezov\u00e9 oceli proti korozi v reduk\u010dn\u00edch prost\u0159ed\u00edch, jako je kyselina chlorovod\u00edkov\u00e1 a z\u0159ed\u011bn\u00e1 kyselina s\u00edrov\u00e1. Minim\u00e1ln\u00ed obsah molybdenu v austenitick\u00e9 nerezov\u00e9 oceli je asi 2%, jako je nerezov\u00e1 ocel 316. Vysoce v\u00fdkonn\u00e9 austenitick\u00e9 nerezov\u00e9 oceli s nejvy\u0161\u0161\u00edm obsahem slitiny obsahuj\u00ed a\u017e 7,5% molybdenu. Molybden p\u0159isp\u00edv\u00e1 k tvorb\u011b feritov\u00e9 f\u00e1ze a ovliv\u0148uje f\u00e1zovou rovnov\u00e1hu. Pod\u00edl\u00ed se na tvorb\u011b n\u011bkolika \u0161kodliv\u00fdch sekund\u00e1rn\u00edch f\u00e1z\u00ed a bude tvo\u0159it nestabiln\u00ed vysokoteplotn\u00ed oxidy, m\u00e1 negativn\u00ed dopad na odolnost proti vysokoteplotn\u00ed oxidaci, je t\u0159eba vz\u00edt v \u00favahu pou\u017eit\u00ed nerezov\u00e9 oceli obsahuj\u00edc\u00ed molybden.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>C<\/strong><\/p>\n<p>Uhl\u00edk stabilizuje a posiluje austenitickou f\u00e1zi. Uhl\u00edk je prosp\u011b\u0161n\u00fd prvek pro nerezovou ocel pou\u017e\u00edvanou v prost\u0159ed\u00ed s vysokou teplotou, jako jsou trubky kotl\u016f, ale v n\u011bkter\u00fdch p\u0159\u00edpadech m\u016f\u017ee m\u00edt \u0161kodliv\u00fd vliv na odolnost proti korozi. Obsah uhl\u00edku ve v\u011bt\u0161in\u011b austenitick\u00e9 nerezov\u00e9 oceli je obvykle omezen na nejni\u017e\u0161\u00ed mo\u017enou \u00farove\u0148. Obsah uhl\u00edku ve sva\u0159ovac\u00edch stupn\u00edch (<a href=\"https:\/\/wldstainless.com\/materials\/austenitic-stainless-steel\/304-304l-stainless-steel\/\">304 l<\/a>, 201L a 316L) je omezena na 0,030%. Obsah uhl\u00edku u n\u011bkter\u00fdch vysoce legovan\u00fdch vysoce v\u00fdkonn\u00fdch jakost\u00ed je dokonce omezen na 0,0201 TP3T.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>N<\/strong><\/p>\n<p>Dus\u00edk stabilizuje a zpev\u0148uje f\u00e1zi austenitu a zpomaluje senzibilizaci karbid\u016f a tvorbu sekund\u00e1rn\u00ed f\u00e1ze. Jak standardn\u00ed austenitick\u00e9 nerezov\u00e9 oceli, tak vysoce v\u00fdkonn\u00e9 austenitick\u00e9 nerezov\u00e9 oceli obsahuj\u00ed dus\u00edk. U n\u00edzkouhl\u00edkov\u00e9ho stupn\u011b (L) m\u016f\u017ee mal\u00e9 mno\u017estv\u00ed dus\u00edku (a\u017e 0,11 TP3T) kompenzovat ztr\u00e1tu pevnosti v d\u016fsledku n\u00edzk\u00e9ho obsahu uhl\u00edku. Dus\u00edk tak\u00e9 pom\u00e1h\u00e1 zlep\u0161it odolnost proti chloridov\u00e9 d\u016flkov\u00e9 a \u0161t\u011brbinov\u00e9 korozi, tak\u017ee n\u011bkter\u00e9 z nejlep\u0161\u00edch korozivzdorn\u00fdch vysoce v\u00fdkonn\u00fdch austenitick\u00fdch nerezov\u00fdch ocel\u00ed maj\u00ed obsah dus\u00edku a\u017e 0,51 TP3T.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Mn<\/strong><\/p>\n<p>Ocel\u00e1rny pou\u017e\u00edvaj\u00ed mangan k dezoxidaci roztaven\u00e9 oceli, tak\u017ee mal\u00e9 mno\u017estv\u00ed manganu z\u016fst\u00e1v\u00e1 ve v\u0161ech nerezov\u00fdch ocel\u00edch. Mangan m\u016f\u017ee tak\u00e9 stabilizovat austenitickou f\u00e1zi a zlep\u0161it rozpustnost dus\u00edku v nerezov\u00e9 oceli. Proto lze v nerezov\u00e9 oceli \u0159ady 200 pou\u017e\u00edt mangan jako n\u00e1hradu \u010d\u00e1sti niklu, aby se zv\u00fd\u0161il obsah dus\u00edku, zlep\u0161ila se pevnost a odolnost proti korozi. K dosa\u017een\u00ed stejn\u00e9ho \u00fa\u010dinku se do n\u011bkter\u00fdch vysoce v\u00fdkonn\u00fdch austenitick\u00fdch nerezov\u00fdch ocel\u00ed p\u0159id\u00e1v\u00e1 mangan.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Cu<\/strong><\/p>\n<p>M\u011b\u010f m\u016f\u017ee zlep\u0161it odolnost nerezov\u00e9 oceli proti korozi v reduk\u010dn\u00edch kyselin\u00e1ch, jako jsou n\u011bkter\u00e9 sm\u011bsn\u00e9 roztoky kyseliny s\u00edrov\u00e9 a fosfore\u010dn\u00e9.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Si<\/strong><\/p>\n<p>Obecn\u011b je k\u0159em\u00edk prosp\u011b\u0161n\u00fdm prvkem v austenitick\u00e9 nerezov\u00e9 oceli, proto\u017ee m\u016f\u017ee zlep\u0161it odolnost oceli proti korozi v koncentrovan\u00e9 kyselin\u011b a v prost\u0159ed\u00ed s vysokou oxidac\u00ed. Uv\u00e1d\u00ed se, \u017ee UNS S30600 a dal\u0161\u00ed speci\u00e1ln\u00ed nerezov\u00e9 oceli s vysok\u00fdm obsahem k\u0159em\u00edku maj\u00ed vysokou odolnost proti d\u016flkov\u00e9 korozi. K\u0159em\u00edk, stejn\u011b jako mangan, lze tak\u00e9 pou\u017e\u00edt k dezoxidaci roztaven\u00e9 oceli, tak\u017ee v oceli v\u017edy z\u016fst\u00e1vaj\u00ed mal\u00e9 oxidick\u00e9 inkluze obsahuj\u00edc\u00ed k\u0159em\u00edk, mangan a dal\u0161\u00ed dezoxida\u010dn\u00ed prvky. P\u0159\u00edli\u0161 mnoho inkluz\u00ed v\u0161ak ovlivn\u00ed kvalitu povrchu produktu.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Nb a Ti<\/strong><\/p>\n<p>Tyto dva prvky jsou siln\u00e9 karbidotvorn\u00e9 prvky a lze je pou\u017e\u00edt m\u00edsto n\u00edzkokarbonov\u00fdch t\u0159\u00edd ke zm\u00edrn\u011bn\u00ed senzibilizace. Karbid niobu a karbid titanu mohou zlep\u0161it pevnost p\u0159i vysok\u00fdch teplot\u00e1ch. <a href=\"https:\/\/wldstainless.com\/materials\/austenitic-stainless-steel\/347-347h-stainless-steel\/\">347<\/a> a nerezov\u00e9 oceli 321 obsahuj\u00edc\u00ed Nb a Ti se b\u011b\u017en\u011b pou\u017e\u00edvaj\u00ed v kotl\u00edch a rafina\u010dn\u00edch za\u0159\u00edzen\u00edch, aby splnily po\u017eadavky na pevnost a sva\u0159itelnost p\u0159i vysok\u00fdch teplot\u00e1ch. Pou\u017e\u00edvaj\u00ed se tak\u00e9 v n\u011bkter\u00fdch deoxida\u010dn\u00edch procesech jako zbytkov\u00e9 prvky ve vysoce v\u00fdkonn\u00fdch austenitick\u00fdch nerezov\u00fdch ocel\u00edch.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>S a P<\/strong><\/p>\n<p>S\u00edra je pro nerezovou ocel dobr\u00e1 i \u0161patn\u00e1. M\u016f\u017ee zlep\u0161it v\u00fdkon obr\u00e1b\u011bn\u00ed, po\u0161kozen\u00edm je sn\u00ed\u017een\u00ed tepeln\u00e9 zpracovatelnosti, zv\u00fd\u0161en\u00ed po\u010dtu inkluz\u00ed sulfidu manganu, co\u017e m\u00e1 za n\u00e1sledek sn\u00ed\u017een\u00ed odolnosti nerezov\u00e9 oceli proti d\u016flkov\u00e9 korozi. Vysoce kvalitn\u00ed austenitick\u00e1 nerezov\u00e1 ocel nen\u00ed snadn\u00e9 tepeln\u011b zpracovat, tak\u017ee obsah s\u00edry by m\u011bl b\u00fdt kontrolov\u00e1n na co nejni\u017e\u0161\u00ed \u00farovni, asi 0,0011 TP3T. S\u00edra se b\u011b\u017en\u011b nep\u0159id\u00e1v\u00e1 jako leguj\u00edc\u00ed prvek do vysoce v\u00fdkonn\u00fdch austenitick\u00fdch nerezov\u00fdch ocel\u00ed. Obsah s\u00edry ve standardn\u00ed nerezov\u00e9 oceli je v\u0161ak \u010dasto vysok\u00fd (0,005% ~ 0,017%), aby se zlep\u0161ila hloubka pr\u016fniku svaru samotavn\u00e9ho sva\u0159ov\u00e1n\u00ed, zlep\u0161il se \u0159ezn\u00fd v\u00fdkon.<\/p>\n<p>Fosfor je \u0161kodliv\u00fd prvek a m\u016f\u017ee nep\u0159\u00edzniv\u011b ovlivnit pracovn\u00ed vlastnosti kov\u00e1n\u00ed a v\u00e1lcov\u00e1n\u00ed za tepla. V procesu chlazen\u00ed po sva\u0159ov\u00e1n\u00ed tak\u00e9 podpo\u0159\u00ed v\u00fdskyt tepeln\u00e9ho prask\u00e1n\u00ed. Proto by m\u011bl b\u00fdt obsah fosforu kontrolov\u00e1n na minim\u00e1ln\u00ed \u00farovni.<\/p>","protected":false},"excerpt":{"rendered":"<p>Chemick\u00e9 slo\u017een\u00ed m\u00e1 velk\u00fd vliv na mikrostrukturu, mechanick\u00e9 vlastnosti, fyzik\u00e1ln\u00ed vlastnosti a korozn\u00ed odolnost oceli. Chrom, molybden, nikl a dal\u0161\u00ed leguj\u00edc\u00ed prvky mohou nahradit vrchol \u00dahel austenitov\u00e9 m\u0159\u00ed\u017eky a st\u0159ed \u0161esti stran krychle \u017eelezo, uhl\u00edk a dus\u00edk jsou um\u00edst\u011bny v meze\u0159e mezi [\u2026]<\/p>","protected":false},"author":1,"featured_media":2210,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[23],"tags":[],"class_list":["post-2248","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/posts\/2248","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/comments?post=2248"}],"version-history":[{"count":3,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/posts\/2248\/revisions"}],"predecessor-version":[{"id":2251,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/posts\/2248\/revisions\/2251"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/media\/2210"}],"wp:attachment":[{"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/media?parent=2248"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/categories?post=2248"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wldstainless.com\/cs\/wp-json\/wp\/v2\/tags?post=2248"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}